MATSE 481: Electron Microscopy and Diffraction Theory

Homepage: http://kriven.mse.uiuc.edu

Textbook and References:
1. D. B. Williams and C. B. Carter, "Transmission Electron Microscopy," Books 1 to 4, Plenum Press (1996)
2. Class notes and handouts
3. A number of references are used.

Catalog Description, Prerequisites and Schedule:

Theory and application of transmission electron microscopy and diffraction with emphasis on thin crystals; electron optics, interference phenomena, interpretation of images and diffraction patterns, specimen preparation, etc. Prerequisite: MATSE 305 or equivalent. Credit: 3 hours or 1 unit. 3 lecture/discussion hours per week.

Course Topics:

1. Basics of electron microscopy
Introduction to SEM and TEM
Scattering and diffraction
Elastic scattering
Inelastic scattering and beam damage
Electron sources
Optics
Lenses, apertures and resolution
The instrument and electron optics
Specimen preparation
2. Diffraction
Diffraction patterns
Thinking in reciprocal space
Diffraction from crystals
Diffraction from small volumes
Stereograms, planar and directional for general symmetry
Indexing diffraction patterns, the general method
Kikuchi diffraction
Obtaining CBED patterns
Using convergent beam techniques
3. Imaging
Imaging in the TEM
Thickness and bending effects
Dark field and weak beam techniques
4. Microchemical analysis by energy dispersive spectroscopy
X-ray spectrometry
The EDS-TEM interface
Qualitative X-ray analysis

Course Objectives:

1. To understand the principles of optics, the different types of glass lenses and how they work, and how they can be combined to form real and virtual images.
2. To understand the physics of different types of scattering events, viz., elastic, plastic, coherent, incoherent, forward and back scattering.
3. Review the dual (particle and wave) nature of electrons.
4. Review the principles of crystallography and systematic extinctions.
5. To understand how an electromagnetic lens works, the coupling of electromagnetic lenses, and effect of lens defects.
6. The construction of an SEM, TEM and STEM, including the function and positioning of apertures, stigmators, deflectors and detectors.
7. Know how to prepare thin TEM specimens of metals, ceramics, polymers and combinations of them (composites), using standard techniques.
8. To be able to take bright field, dark field, centered dark field and weak beam images, while correcting for astigmatism.
9. To be able to take a selected area diffraction pattern (SAD), convergent beam (CBED), Kossel-Möllenstedt patterns, as well as Kikuchi patterns, and use the latter as guides for orientation in reciprocal space.
10. To have some familiarity with the techniques of electron backscattered diffraction patterns (EBPD's) or orientation imaging microscopy (OIM) in SEM.
11. To plot and manipulate both planar and directional stereograms, and use them to both predict, as well as to analyze, SAD or Kikuchi patterns for any crystal system (including non-orthogonal systems such as monoclinic and triclinic).
12. To know the method of microchemical analyses by energy dispersive X-ray spectroscopy (EDS) and wavelength dispersive spectroscopy (WDS). Students should be familiar with both the standard (K-factor ratio) and standardless methods for quantitative evaluation of elements present in a specimen.

Course Outcomes:

1. an understanding of image formation by glass and electromagnetic lenses.
2. an understanding of the physics of scattering
3. an understanding of the construction of various types of electron microscopes, the function of the various parts and methods of image formation.
4. an understanding of methods of sample preparation for SEM and TEM.
5. ability to index electron diffraction patterns and interpret Kossel- Möllenstedt and Kikuchi patterns.
6. ability to utilize EDS and WDS results for microchemical analysis.

Assessment Tools:

1. Seven sets of homework problems were formulated by the instructor, complemented by teams of 3-4 students each. The students prepared questions on any topic covered or any topic that could receive more attention for the sake of clarity. The final questions were prepared in consultation with each team by the instructor. The students graded each homework assignment, and explained the solution and common mistakes before the class.
2. Subsequent, more involved and challenging homework projects were prepared by the instructor.
3. One 1 and 1/2 to 2 hour mid-term exam and a 3-hour final exam.
4. One project (sometimes written, always oral, sometimes a poster) was done by each student. The project was relevant to the undergraduate student's interest or to the graduate student's research topic.

Contribution of Course to Meeting the Professional Component: 100%

Prepared by: Waltraud Kriven, March 2001