MATSE 452: Polymer Characterization Laboratory

Homepage:

Textbook: Class notes.

References:
1. Notes from MATSE 350.
2. Collins, Bares and Billmeyer, "Experiments in Polymer Science,"
Wiley-Interscience, New York, 1973

Catalog Description, Prerequisites and Schedule:

Characterizes polymer materials experimentally to investigate molecular, microstructural, and macroscopic aspects of their mechanical, thermal, electrical, and optical properties. A team project is an integral part of this course. Prerequisite: Materials Science and Engineering 350 or consent of instructor. 4 credits or 1 unit. 1 hour lecture, 4 hours lab, 3 hours independent project/week

Course Topics:

1. Polymer synthesis
free radical polymerization, copolymerization.
2. Characterization
dilute solution viscometry; gel permeation chromatography; infrared spectroscopy; gel electrophoresis; differential scanning calorimetry.
3. Processing
compression molding; influence of processing on density.
4. Mechanical behavior
dynamic mechanical spectroscopy; time-temperature superposition.

Course Objectives:

1. To teach students a hands-on acquaintance with important modern polymer laboratory techniques of synthesis, characterization, processing, and mechanical behavior.
2. To teach students to analyze and interpret results of laboratory experiments; to formulate critical evaluations of both positive results (results that were as expected) and negative results (results that were not as expected).
3. To teach students techniques of experimental data acquisition (manual and computer-based); techniques of plotting and analysis of data; and effective communication of findings in the form of a concise laboratory report.
4. To teach students to design and implement in a group setting an open-ended team project to complement the predesigned aspect of this laboratory; to prepare a written and oral presentation of this project.

Course Outcomes:

1. Given an unidentified polymer sample, be able to determine its thermal transition temperatures, solubility, and flammability.
2. Given an unidentified polymer sample, be able to determine its molecular weight, molecular weight distribution, and chemical composition.
3. Be able to predict the influence on mechanical and processing properties of changing the sample's molecular weight and molecular weight distribution.
4. Given a desired range of operating temperature, be able to predict how to select a polymer sample whose chemical makeup will give it desirable thermal relaxation properties (melting temperature, glass transition temperature) and whose molecular makeup will give it desirable processability, mechanical and electrical relaxation processes (rate dependence of relaxation functions).
5. Given an open-ended request to perform as a team of 2-3 students a laboratory project of unspecified content during the limited time of the semester and with the resources available to the laboratory, design and execute this project, summarize it in written form, and communicate it orally to the class.

Assessment Tools:

1. A laboratory report on each of the predesigned laboratory projects, written by the laboratory team of 2-3 students.
2. An oral and written presentation of the open-ended team project.
3. Pre-lab quizzes administered from time to time just before the laboratory begins.

Contribution of Course to Meeting the Professional Component

100%

Prepared by:

Steve Granick, February,2001